Physician
Ophthalmology
Dr. David W. MacMillan, MD
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David MacMillan practices Ophthalmology. He researched medicine at University of Virginia School of Medicine. David MacMillan is also a published physician. He has 61 publication published. The most recent publication is: Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis.
Publications
- Stereoselection in the Prins-pinacol synthesis of acyltetrahydrofurans.
- Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral.
- A general strategy for the synthesis of cladiellin diterpenes: enantioselective total syntheses of 6-acetoxycladiell-7(16),11-dien-3-ol (deacetoxyalcyonin acetate), cl...
- Design of a new cascade reaction for the construction of complex acyclic architecture: the tandem acyl-claisen rearrangement.
- Enantioselective Claisen rearrangements: development of a first generation asymmetric acyl-Claisen reaction.
- Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol.
- New strategies in organic catalysis: the first enantioselective organocatalytic Friedel-Crafts alkylation.
- Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis.
- Discovery of an ?-amino C-H arylation reaction using the strategy of accelerated serendipity.
- Enantioselective ?-arylation of carbonyls via Cu(I)-bisoxazoline catalysis.
- Collective synthesis of natural products by means of organocascade catalysis.
- Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.
- Enantioselective ?-arylation of aldehydes via the productive merger of iodonium salts and organocatalysis.
- Organocatalysis.
- Direct and enantioselective {alpha}-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis.
- Enantioselective ?-benzylation of aldehydes via photoredox organocatalysis.
- Mechanistic complexity in organo-SOMO activation.
- Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway.
- Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins.
- Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes.
- Enantioselective polyene cyclization via organo-SOMO catalysis.
- The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.
- Nine-step enantioselective total synthesis of (+)-minfiensine.
- Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis.
- Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway.
- Enantioselective aldehyde alpha-nitroalkylation via oxidative organocatalysis.
- Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation.
- Cycle-specific organocascade catalysis: application to olefin hydroamination, hydro-oxidation, and amino-oxidation, and to natural product synthesis.
- Enantioselective organo-singly occupied molecular orbital catalysis: the carbo-oxidation of styrenes.
- The advent and development of organocatalysis.
- Merging photoredox catalysis with organocatalysis: the direct asymmetric alkylation of aldehydes.
- Total synthesis and structural revision of callipeltoside C.
- Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes.
- Enantioselective organocatalytic transfer hydrogenation reactions using Hantzsch esters.
- Organocatalytic vinyl and Friedel-Crafts alkylations with trifluoroborate salts.
- Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes.
- Enantioselective organocatalysis using SOMO activation.
- Organocatalytic transfer hydrogenation of cyclic enones.
- Enantioselective organocatalytic amine conjugate addition.
- Enantioselective organocatalytic reductive amination.
- Enantioselective organo-cascade catalysis.
- Enantioselective organocatalytic intramolecular Diels-Alder reactions. The asymmetric synthesis of solanapyrone D.
- Enantioselective organocatalytic alpha-fluorination of aldehydes.
- Total synthesis of brasoside and littoralisone.
- Enantioselective organocatalytic cyclopropanations. The identification of a new class of iminium catalyst based upon directed electrostatic activation.
- Enantioselective organocatalytic hydride reduction.
- The importance of iminium geometry control in enamine catalysis: identification of a new catalyst architecture for aldehyde-aldehyde couplings.
- Two-step synthesis of carbohydrates by selective aldol reactions.
- Enantioselective organocatalytic direct aldol reactions of alpha-oxyaldehydes: step one in a two-step synthesis of carbohydrates.
- Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition-cyclization strategy: synthesis of (-)-flustramine B.
- Direct and enantioselective organocatalytic alpha-chlorination of aldehydes.
- The direct and enantioselective organocatalytic alpha-oxidation of aldehydes.
- The first Suzuki cross-couplings of aryltrimethylammonium salts.
- The first enantioselective organocatalytic Mukaiyama-Michael reaction: a direct method for the synthesis of enantioenriched gamma-butenolide architecture.
- Development of a new Lewis acid-catalyzed [3,3]-sigmatropic rearrangement: the allenoate-Claisen rearrangement.
- A general method for the enantioselective synthesis of pantolactone derivatives.
- The enantioselective organocatalytic 1,4-addition of electron-rich benzenes to alpha,beta-unsaturated aldehydes.
- The first direct and enantioselective cross-aldol reaction of aldehydes.
- The first general enantioselective catalytic Diels-Alder reaction with simple alpha,beta-unsaturated ketones.
- Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis.
Schools
University of Virginia Main Campus
Henry Ford Hospital
Doctors Specialties
- Ophthalmology
Accepted Insurances
Education
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Henry Ford Hospital - Wayne State University -
University of Virginia School of Medicine
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